2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl (t-Bu)PhCPhos - Names and Identifiers
Name | 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl (t-Bu)PhCPhos
|
Synonyms | 2-(t-ButyL phosphino)-2',6'-dimethyL 2-[(tert-Butyl)phenylphosphino]-2′,6′-bis(N,N-dimethylamino)biphenyl 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl (t-Bu)PhCPhos 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, (t-Bu)PhCPhos 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine
|
CAS | 1660153-91-2
|
2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl (t-Bu)PhCPhos - Physico-chemical Properties
Molecular Formula | C26H33N2P
|
Molar Mass | 404.53 |
Melting Point | 112 °C |
Appearance | Powder |
Color | white to off-white |
Storage Condition | 2-8℃ |
2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl (t-Bu)PhCPhos - Introduction
2-(t-Butylphenylphosphino)-2 ',6'-dimethylamino-1,1 '-biphenyl (t-Bu)PhCPhos (t-BuPhCPhos) is an organic phosphorus compound with a chemical formula of C22H25NP and a molecular weight of 335.43g/mol.
The compound is an electron-rich ligand with good coordination ability and three-dimensional volume. It is widely used in metal-catalyzed reactions in the field of organic synthesis, especially in transition metal-catalyzed C- C bond formation reactions. It can form stable complexes with a variety of transition metals and participate as ligands in different catalytic reactions, such as hydrogenation, carbon-phosphorus bond activation and hydride transfer.
The preparation method of t-BuPhCPhos is generally realized by a conventional method for synthesizing organic phosphorus compounds. In the preparation process, 2-bromotoluene is first synthesized, and then reacted with diethylamine to generate diethylamine -2-methyl phenyl phosphine compound, and then the target compound t-BuPhCPhos is synthesized by thermochemical reaction.
When using t-BuPhCPhos for catalytic reactions, it is necessary to pay attention to its safety. It is an organic fluorescent substance and should be protected from prolonged exposure to light to prevent its decomposition. Follow the safety instructions for chemical experiments and take appropriate protective measures, such as wearing chemical protective gloves, goggles and protective clothing. In addition, t-BuPhCPhos is a flammable solid and should be stored in a sealed container and kept away from fire and high temperatures.
Last Update:2024-04-10 22:29:15